Sample preparation

Sample preparation - context
Sample preparation - motivation
Purpose of sample preparation
Overview of preparation methods
     Liquid liquid extraction (LLE)
     Solid phase extraction (SPE)
     Solid phase microextraction (SPME)
     Purge and trap (PT)
     (Accelerated) Solvent extraction ((A)SE)
     Supercritical fluid extraction (SFE)
      Filter Techniques (FT)
           General description of FT
           Illustration of FT
           Detailed description of FT
Box 10 Filtration
Box 11 Sorbents
Box 12 Preconcentration
Self test
Problems
End of chapter


General description of filter techniques

Principle:

  1. Sorption of analyte(s) from air A to sorbent material P in the filter: volumes up to several hundred m3 air are sucked through one filter by high volume sampler



    Note: This is an expression for partition equilibrium (note: non-equilibrium conditions prevail if flow rates are too high to allow attainment of local equilibrium for analyte(s) between the air and the sorbent phases)

  2. Thermal desorption of analyte from sorbent in an oven coupled to a GC system

advantage:

simultaneous sampling and extraction
(fewer sources of systematic error)

disadvantage:

potential breakthrough of analyte through filter