Purge: phase transfer of analyte(s) with relatively large air/water partition constants from an aqueous phase W into gas bubbles created by purging the sample
non-volatile interferents remain in water sample
Trap: Phase transfer of analyte(s) from purge gas to solid sorbent in a filter unit
pre-concentration of analyte in the sorbent
Thermal desorption of analyte from the sorbent in an oven connected to the GC column
advantage:
exhaustive extraction of 'volatile' analytes
from water samples
disadvantage:
potential breakthrough of analyte through sorbent filter