Equilibrium partitioning of organic compounds

Some fundamentals ...
Summary and further information
Self test
Problems
     Question 1
           Answer
     Question 2
           Answer
     Question 3
           Answer
     Question 4
           Answer
     Question 5
           Answer
     Question 6
           Answer
     Question 7
           Answer
     Question 8
           Answer
     Question 9
           Answer
     Question 10
           Answer
     Question 11
           Answer
     Question 12
           Answer
     Question 13
           Answer
     Question 14
           Answer
     Question 15
     Question 16
     Question 17
     Question 18
           Answer
Advanced problems
FAQ

Question 5

A system with an oil phase and a water phase contains a very tiny amount of chemical A. Now you add another chemical, B. Will the partitioning of B in the system be influenced by the presence of A?

Help: What does the situation look like when you add only chemical B to the system in tiny amounts? What exactly determines the partition constant between two phases?

Answer: The presence of A has no effect on the partitioning of B. This is due to the fact that A is present in such a low concentration (i.e., it is so dilute) that it does not interact with B because molecules of A and B hardly ever meet in the phases. Hence, the partition behavior of B is only determined by its interactions with the two phases oil and water.

 

Download this page as a pdf