Equilibrium partitioning of organic compounds

Some fundamentals ...
     Preliminary note
     Introduction
     Condensed phase and gas phase
     2 condensed phases
     3 phase system
     Partitioning between various phases
Summary and further information
Self test
Problems
Advanced problems
FAQ

3 phase system: 2 condensed phases and a gas phase

If all three phases - water, oil and gas phase - occur together then water and oil molecules will partition into the two other phases in the same way as they did in the two-phase scenarios. That means the presence of the oil phase has no influence on the partitioning of water into the gas phase and the presence of the gas phase has no influence on the partitioning of water into the oil phase. And the same is true, of course, for the oil molecules. A situation similar to this three-phase problem occurs in the environment if crude oil or gasoline leaks into the environment. The organic molecules that constitute the crude-oil or gasoline phase will then partition into the air and any available aqueous phase.

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